Use of azomethine-bridged phenolic metallophthalocyanines for sensitization of TiO2
Yazarlar (7)
Melek Koç
Karadeniz Technical University, Türkiye
Cansu Albay Karadeniz Technical University, Türkiye
Prof. Dr. İlknur Altın Karadeniz Teknik Üniversitesi, Türkiye
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Prof. Dr. Halil Gökce Giresun Üniversitesi, Türkiye
Prof. Dr. İsmail Değirmencioğlu Karadeniz Teknik Üniversitesi, Türkiye
Münevver Sökmen Konya Gıda ve Tarım Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Desalination and Water Treatment (Q2)
Dergi ISSN 1944-3994 Dergi Bilgileri (2017)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2017
Cilt / Sayı / Sayfa 59 / 1 / 191–201 DOI 10.5004/dwt.2017.0259
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S1944398624130196
UAK Araştırma Alanları
Anorganik Kimya
Özet
A group of novel azomethine-bridged phenolic metallophtalocyanines (substituted at nonperipheral position, MPc) were synthesized, characterized and used as sensitizer. Phthalocyanine derivatives (containing TiO(II), Fe(II), Co(II), Ni(II) and Zn(II) ions in the center of phtalocyanine) were immobilized on TiO2 photocatalyst using a wet deposition method. MPc/TiO2 nanocomposites have been tested for their photocatalytic reduction ability of Cr(VI) ions in aqueous solution under near visible light irradiation. The results demonstrated that the presence of the sensitizer is certainly beneficial for the photocatalytic activity of TiO2, confirming the significant role of substitution and metal co-ordination in the center of the phthalocyanine ring. Photoreduction results show that the all composite materials exposed significantly higher Cr(VI) removal performance than bare TiO2. Consequently, MPc sensitized TiO2 …
Anahtar Kelimeler
Dye sensitization | Metallophtalocyanines | Photocatalysis
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 3
Scopus 3
Google Scholar 5
Use of azomethine-bridged phenolic metallophthalocyanines for sensitization of TiO2

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