Synthesis and Spectro-Electrochemical Properties of New Metallophthalocyanines Having High Electron Transfer Capability
Yazarlar (7)
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Seçil Kırlangıç Ataşen İstanbul Gelişim Üniversitesi, Türkiye
Prof. Dr. İsmail Yılmaz İstanbul Teknik Üniversitesi, Türkiye
İzzet Yalçın Karadeniz Technical University, Türkiye
Murat Erman Karadeniz Technical University, Türkiye
Prof. Dr. Yasemin Ünver Karadeniz Teknik Üniversitesi, Türkiye
Prof. Dr. İsmail Değirmencioğlu Karadeniz Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2021) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2021 |
| Cilt / Sayı / Sayfa | 1231 / 1 / 129677–0 | DOI | 10.1016/j.molstruc.2020.129677 |
| Makale Linki | http://dx.doi.org/10.1016/j.molstruc.2020.129677 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| It is important to synthesis and examine the redox properties of phthalocyanines and related macrocycles in order to reveal their possible applications. In this paper, new Zn2+, Co2+ and Mn2+ phthalocyanine complexes containing substituted 1,2,4-triazole groups on peripheral positions have been prepared and characterized by classical methods and electrochemistry in detail. The use of triethylamine and acetone combination in the synthesis of nitrile structures 3a and 3b, the starting compounds for phthalocyanines, both increased yield of products and shortened reaction time compared to classical synthesis of nitrile structures. The electron transfer capability of new metallophthalocyanines (ZnPcs, CoPcs and MnPcs) was investigated in detail via cyclic voltammetry (CV), square wave voltammetry (SWV) and in situ UV–vis spectroelectrochemistry. For ZnPcs, these experiments demonstrated that the complexes … |
| Anahtar Kelimeler |
| electrochemistry | Metallophthalocyanine | spectroelectrochemistry | triazole |
Science Direct
Synthesis and Spectro-Electrochemical Properties of New Metallophthalocyanines Having High Electron Transfer Capability
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 13 |
| Scopus | 13 |
| Google Scholar | 18 |