Synthesis, aggregation and spectroscopic studies of novel water soluble metal free, zinc, copper and magnesium phthalocyanines and investigation of their anti-bacterial properties
 
Yazarlar (6)
Prof. Dr. Rıza BAYRAK Sinop Üniversitesi, Türkiye
Prof. Dr. Hakkı Türker Akçay Recep Tayyip Erdoğan Üniversitesi, Türkiye
Prof. Dr. Fatih Şaban Beriş Recep Tayyip Erdoğan Üniversitesi, Türkiye
Ertan Şahin Atatürk Üniversitesi, Türkiye
Prof. Dr. Hacer Bayrak Karadeniz Teknik Üniversitesi, Türkiye
Prof. Dr. Ümit Demirbaş Karadeniz Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy (Q2)
Dergi ISSN 1386-1425 Dergi Bilgileri (2014)
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 12-2014
Cilt / Sayı / Sayfa 133 / 1 / 272–280 DOI 10.1016/j.saa.2014.05.075
Makale Linki https://doi.org/10.1016/j.saa.2014.05.075
UAK Araştırma Alanları
Anorganik Kimya
Özet
In this study, novel phthalonitrile derivative (3) was synthesized by the reaction between 4-nitrophthalonitrile (2) and a triazole derivative (1) containing pyridine moiety. Crystal structure of compound (3) was characterized by X-ray diffraction. New metal free and metallo-phthalocyanine complexes (Zn, Cu, and Mg) were synthesized using the phthalonitrile derivative (3). Cationic derivatives of these phthalocyanines (5, 7, 9, and 11) were prepared from the non-ionic phthalocyanines (4, 6, 8, and 10). All proposed structures were supported by instrumental methods. The aggregation behaviors of the phthalocyanines (4–11) were investigated in different solvents such as dimethylsulfoxide (DMSO), N,N-dimethylformamide (DMF), chloroform and water. Water soluble cationic Pcs (5, 7, 9, and 11) aggregated in water and sodium dodecyl sulfate was used to prevent the aggregation. The second derivatives of the UV–Vis …
Anahtar Kelimeler
Aggregation | Anti-bacterial activity | Cationic phthalocyanine | Sodium dodecylsulfate | Thermal stability | X-ray diffraction