Comparative determination of the time-dependent accumulation of metal oxides in the landfill gas combustion chamber deposits using SEM-EDS, XRF and ICP OES
Yazarlar (3)
Doç. Dr. Orhan Sevimoğlu Gebze Teknik Üniversitesi, Türkiye
Dr. Öğr. Üyesi Özge ÖSTÜRK SÖMEK Sinop Üniversitesi, Türkiye
Öğr. Gör. Fikret Yıldız Gebze Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Microchemical Journal (Q1)
Dergi ISSN 0026-265X Dergi Bilgileri (2024)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 10-2024
Kabul Tarihi Yayınlanma Tarihi 01-12-2024
Cilt / Sayı / Sayfa 207 / 1 / 112042–0 DOI 10.1016/j.microc.2024.112042
Makale Linki http://dx.doi.org/10.1016/j.microc.2024.112042
UAK Araştırma Alanları
Hava Kirliliği ve Kontrolü İklim Değişikliği Nanoteknoloji
Özet
Non-purified landfill gas (LFG) leads to the formation of complex deposits in combustion chambers due to impurities such as siloxanes, sulfur compounds, and organometallic compounds containing elements such as Si, S, Sb, Sn. This study focused on identifying the elemental composition of deposits from four combustion chambers using analytical techniques including SEM-EDS, WDXRF, and microwave digestion ICP OES. The dominant element, Si, with concentrations (wt%) in the deposits was measured by SEM-EDS, ICP-OES, and WDXRF, respectively, as follows: 17.04 ± 8.59, 21.89 ± 4.39, and 16.63 ± 0.94 for cylinder head deposits, and 13.28 ± 6.97, 15.40 ± 5.40, and 12.64 ± 1.64 for piston head deposits. Excluding C, O and N, which could not be analyzed by all three techniques, the multi-analytical approaches demonstrated strong correlations between EDS results and those obtained from WDXRF and …
Anahtar Kelimeler
Deposit accumulation | Elemental analysis | Landfill gas | Spectroscopy analysis