| Bildiri Türü | Tebliğ/Bildiri | Bildiri Dili | İngilizce |
| Bildiri Alt Türü | |||
| Bildiri Niteliği | Web of Science Kapsamındaki Kongre/Sempozyum | ||
| DOI Numarası | 10.1016/j.poly.2014.01.005 | ||
| Kongre Adı | 4. Ulusal Kristalografi Toplantısı | ||
| Kongre Tarihi | 17-05-2014 / 19-05-2014 | ||
| Basıldığı Ülke | Türkiye | Basıldığı Şehir | Diyarbakır |
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
|
||
| Özet |
| Three new coordination compounds, {[Cu(μ3-tdp)(phen)]·2H2O}n (1), {[Cu(μ3-tdp)(bipy)]·H2O}n (2), [Cu2(μ2-tdp)(phen)4](NO3)2·2H2O (3) [tdpH2 = 3,3′-thiodipropionic acid, phen = 1,10-phenanthroline, bipy = 2,2′-bipyridine] were synthesized and characterized by the IR spectroscopy, elemental analysis, magnetic measurements and single crystal X-ray diffraction. Thermal behaviors and thermochromic properties of the complexes were investigated in detail. Complexes 1 and 2 are 1D coordination polymers while complex 3 is dinuclear structure. In complexes 1 and 2, the tdp acts as a tridentate bridging ligand to coordinate the two different Cu(II) centers to form 1D chain, which are extended into a 3D networks by hydrogen bonding and π⋯π interactions. The 3,3′-thiodipropionate ligand adopts a new coordination mode in 3. Furthermore, complex 3 changed the color from blue to green at 140 °C at solid state. |
| Anahtar Kelimeler |
| 3,3′-Thiodipropionate complexes | Coordination polymers | Copper(II) complexes | Dinuclear complex | Thermochromism |
| Dergi Adı | POLYHEDRON |
| Kısa Adı | POLYHEDRON |
| Yayıncı | PERGAMON-ELSEVIER SCIENCE LTD |
| Açık Erişim | Hayır |
| ISSN | 0277-5387 |
| E-ISSN | 1873-3719 |
| Wos Quartile | Q2 |
| Scopus Quartile | Q2 |
| Tarandığı Indeksler | SCIE , Scopus |
| WoS Kategoriler | CHEMISTRY, INORGANIC & NUCLEAR | CRYSTALLOGRAPHY |
| Scopus Kategoriler | INORGANIC CHEMISTRY | MATERIALS CHEMISTRY | PHYSICAL AND THEORETICAL CHEMISTRY |