One dimensional coordination polymers of copper II cobalt II zinc II and cadmium II with glutarate and N methylimidazole
Yazarlar (4)
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Öğr. Gör. Yalçın Kılıç Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Orhan Büyükgüngör Ondokuz Mayis University Faculty Of Science And Arts, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polyhedron (Q2)
Dergi ISSN 0277-5387 Dergi Bilgileri (2014)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2014
Cilt / Sayı / Sayfa 67 / 1 / 122–128 DOI 10.1016/j.poly.2013.08.068
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
Four coordination polymers, namely, {[Co(μ-glu)(nmim)2]·2H2O}n (1), [Cu(μ-glu)(nmim)2]n (2), {[Zn(μ-glu)(nmim)2]·2H2O}n (3) and [Cd(μ-glu)(nmim)2] (4) (glu = glutarate, nmim = N-methylimidazole), have been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis and single-crystal X-ray diffraction techniques. Moreover, the photoluminescence properties of 3 and 4 have been investigated. Structural analyses reveal that all the complexes exhibit one-dimensional (1D) linear chain structures bridged by the glutarate ligand, which further form 3D supramolecular networks via intermolecular π⋯π, C–H⋯π and weak hydrogen bonding interactions. In the complexes, the glu ligand adopts the bis-monodentate and bis-bidentate bridging modes through two and four carboxylate oxygen atoms, respectively. The distorted octahedral geometry for complexes 2 and 4 and tetrahedral …
Anahtar Kelimeler
Coordination polymers | Glutarate complex | N-Methylimidazole complex
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 9
Scopus 10
Google Scholar 11
One dimensional coordination polymers of copper II cobalt II zinc II and cadmium II with glutarate and N methylimidazole

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