Two dimensional coordination polymers with3 30 thiodipropionate An unprecedented coordinationmode and strong hydrogen bond network
Yazarlar (4)
Prof. Dr. Mürsel Arıcı Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Orhan Büyükgüngör Ondokuz Mayis University Faculty Of Science And Arts, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q2) | ||
| Dergi ISSN | 0277-5387 Dergi Bilgileri (2014) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2014 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-01-2014 |
| Cilt / Sayı / Sayfa | 67 / 1 / 456–463 | DOI | 10.1016/j.poly.2013.09.040 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S0277538713007067 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Four novel coordination polymers, namely [Co(μ3-tdp)(ina)2]n (1), [Cu(μ3-tdp)(ina)2]n (2), [Zn(μ3-tdp)(ina)2]n (3) and [Zn(μ3-tdp)(na)2]n (4) [tdp: 3,3′-thiodipropionate, ina: isonicotinamide and na: nicotinamide], were synthesized and structurally characterized by elemental analysis, IR and single-crystal X-ray diffraction techniques. Each M(II) ion (M(II)double bondCo(II) in 1, Cu(II) in 2, Zn(II) in 3 and Zn(II) in 4) is coordinated by two nitrogen atoms of two different pyridine rings and four oxygen atoms from three different tdp ligands, forming distorted octahedral geometries. The tdp ligand exhibits an unprecedented coordination mode, namely the μ3-κO,O′:κO″:κO″′-bridging mode. Single crystal X-ray diffraction analysis results demonstrated that complexes 1–4 exhibit 2D layers with a point symbol of 33·43·54, which are extended into 3D supramolecular frameworks by R22(8) hydrogen-bonding motifs. Thermal … |
| Anahtar Kelimeler |
| 3,3′-Thiodipropionate complex | 3,3′-Thiodipropionic acid | Isonicotinamide complex | Nicotinamide complex | Two-dimensional complex |
Science Direct
Two dimensional coordination polymers with3 30 thiodipropionate An unprecedented coordinationmode and strong hydrogen bond network
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| Web of Science | 3 |
| Scopus | 4 |
| Google Scholar | 3 |