Facile Synthesis and Crystal Structures of NewAmmonium Sulfonates CA DNBS and TEA TMBS
Yazarlar (7)
Islam Ullah Khan
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Muhammad Nadeem Arshad Center Of Excellence For Advanced Materials Research, Suudi Arabistan
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Hafiz Mubasharurrehman
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Ayesha Munır Government College University Lahore, Pakistan
Saba Humayun
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Abdullah M Asırı
Center Of Excellence For Advanced Materials Research, Suudi Arabistan
Center Of Excellence For Advanced Materials Research, Suudi Arabistan
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Jiegou Huaxue (Q4) | ||
| Dergi ISSN | 0254-5861 Dergi Bilgileri (2013) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2013 |
| Cilt / Sayı / Sayfa | 32 / 10 / 1465–1474 | DOI | – |
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The title compounds, C12H10N3O7SCl (I) and C15H27NO3S (II), crystallize in the monoclinic system, space group P21/c with a= 7.3995 (1), b= 27.8489 (6), c= 9.8246 (2) Å, β= 131.349 (1) º, V= 1519.82 (5) Å3, Z= 4, F (000)= 768, Rint= 0.033 and S= 1.03 for I, and in the orthorhombic system, space group Pbca with a= 8.6227 (1), b= 16.1480 (4), c= 23.8774 (6) Å, V= 3324.67 (12) Å3, Z= 8, F (000)= 1312, Rint= 0.024 and S= 1.04 for II. We have devised a convenient procedure for the synthesis of fused organic salts resulting from 1: 1 proton-transfer, using an amine and a derivative of benzenesulfonic acid. The synthesized salts have a number of applications ranging from their consumption as eco-friendly solvents and catalysts in organic syntheses, to being used as efficient precursors for the production of sulfa drugs. Structures of compounds 3-chloroanilinium 2, 4-dinitrobenzenesulfonate (CA-DNBS) and triethylaminium 2, 4, 6-trimethylbenzenesulfonate (TEA-TMBS) were determined by single-crystal X-ray diffraction studies and infrared spectroscopy. |
| Anahtar Kelimeler |
| 3-chloroanilinium 2,4-dinitrobenzenesulfonate | Ammonium sulfonates | Crystal structure | Ionic liquids | Triethylaminium 2,4,6-trimethylbenzenesulfonate |
