A mononuclear mixed salicylato nicotinamide complex of Zn II with penta and hexa coordination sites a novel framework structure
Yazarlar (4)
Prof. Dr. Dursun Ali Köse Hitit University, Türkiye
Prof. Dr. Ahmet Nedim Ay Hacettepe Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Ondokuz Mayis Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of the Iranian Chemical Society (Q2) | ||
| Dergi ISSN | 1735-207X Dergi Bilgileri (2012) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2012 |
| Cilt / Sayı / Sayfa | 9 / 4 / 591–597 | DOI | 10.1007/s13738-012-0072-9 |
| Makale Linki | http://link.springer.com/10.1007/s13738-012-0072-9 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The title compound, diaqua(bissalicylato-κO)(bisnicotinamide-κN)zinc(II)][bis(triaqua (monosalicylato-κO)(mononicotinamide-κN)zinc(II)salicylate, includes three Zn(II) ions, four nicotinamide ligands, six salicylate ligands and eight coordinated aqua ligands in the asymmetric unit in complex structure. The geometry around one of the Zn(II) ions is a slightly distorted octahedron, of which the equatorial plane is formed by two carboxylate oxygens and two aqua oxygens, while the axial positions are occupied by two pyridyl nitrogen atoms. The other Zn(II) ions adopt fivefold coordinations with one carboxylate oxygen atom from salicylate ligand, one N atom from nicotinamide ligand and three oxygen atoms from aqua ligands. In addition, there are two salicylate anions in the unit cell that are not coordinated. They provide charge balance as counter-ions in the complex framework. |
| Anahtar Kelimeler |
| Hexa-coordinated Zn(II) | Mixed-ligand complexes | Nicotinamide complexes | Penta-coordinated Zn(II) | Salicylic acid complexes | Zn(II) complexes |
| Atıf Sayıları | |
| Web of Science | 18 |
| Scopus | 19 |
| Google Scholar | 20 |