Synthesis and Crystal Structure ofTrans bis acesulfamato O tetraaquazinc II
Yazarlar (3)
Prof. Dr. Onur ŞAHİN Ondokuz Mayis University Faculty of Science And Arts, Türkiye
Prof. Dr. Hasan Içbudak Ondokuz Mayis University Faculty of Science And Arts, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis University Faculty of Science And Arts, Türkiye
Ondokuz Mayis University Faculty of Science And Arts, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Jiegou Huaxue (Q4) | ||
| Dergi ISSN | 0254-5861 Dergi Bilgileri (2010) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2010 |
| Cilt / Sayı / Sayfa | 29 / 7 / 1047–1050 | DOI | – |
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
|
||
| Özet |
| The title compound, trans-bis (acesulfamato-O) tetraaquazinc (II)(I, C8 H16 N2 O12 S2 Zn), crystallizes in the triclinic system, space group P1̄ with a= 5.1638 (5), b= 8.5338 (9), c= 9.9583 (9) Å, α= 74.325 (8), β= 81.112 (7), γ= 75.800 (8), V= 407.77 (7) Å3, Z= 1, F (000)= 236, Rint= 0.085, T= 296 K, the final R= 0.029 and wR= 0.078 for 1832 observed reflections with I> 2σ (I). The ZnII centre resides on a centre of symmetry and has a distorted octahedral geometry. The basal plane is defined by two carbonyl O atoms of two monodentate trans-oriented acesulfamato ligands and two trans-aqua ligands. The axial positions in the octahedron are occupied by two trans-aqua ligands. Intermolecular OH⋯ O hydrogen bonds produce R22(8) and R22(16) rings, which lead to two-dimensional polymeric chains. |
| Anahtar Kelimeler |
| Complex | Crystal structure | Hydrogen bonds | Octahedral | Zinc(II) |
