Imidazolium salicylaldimine frameworks for the preparation of tridentate N heterocyclic carbene ligands
Yazarlar (4)
Mahmut Ulusoy
Ege Üniversitesi, Türkiye
Ege Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Ondokuz Mayis Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
Bekir Çetinkaya Ege Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Organometallic Chemistry (Q2) | ||
| Dergi ISSN | 0022-328X Dergi Bilgileri (2008) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2008 |
| Cilt / Sayı / Sayfa | 693 / 10 / 1895–1902 | DOI | 10.1016/j.jorganchem.2008.02.017 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0022328X08001368 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Sterically hindered salicylaldimine functionalized imidazolium salts 2 have been prepared. The structures of the synthesized compounds were determined by spectroscopic techniques. The reaction of these salts containing arylmethyl-N chain (aryl: phenyl (2a), 2,4,6-trimethylphenyl (2b), 2,3,4,5,6-pentamethylphenyl (2c)) with Pd(OAc)2 in boiling toluene afforded Pd(II) complexes 3 in high yields. The X-ray structure of 1-[3-(3,5-di-tert-butyl-2-oxophenyl)propyliminato]-3-(2,4,6-trimethylbenzyl)imidazol-2-ylidenebromopalladium(II) (3b) has been determined. The Suzuki–Miyaura reaction was used to investigate their activity as catalysts either prepared in situ or from well-defined complexes. They are efficient when activated arylbromides are used as substrates. |
| Anahtar Kelimeler |
| Bulky salicylaldimine | Carbene-imine ligands | N-heterocyclic carbene | Salicylaldiminato-NHC | Suzuki-Miyaura | Tridentate ligands |
Science Direct
Imidazolium salicylaldimine frameworks for the preparation of tridentate N heterocyclic carbene ligands
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 21 |
| Scopus | 22 |
| Google Scholar | 26 |