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| Dergi Adı | Analytical Sciences X Ray Structure Analysis Online | ||
| Dergi ISSN | 1348-2238 | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2008 |
| Cilt / Sayı / Sayfa | 24 / 9 / – | DOI | 10.2116/analscix.24.x211 |
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The title compound, tetraquaorotatonickel (II) monohydrate, C5H12N2O9Ni, crystallizes in the monoclinic space group P1 with the following unit-cell parameters: a= 7.2282 (4) Å, b= 8.2959 (4) Å, c= 10.0611 (5) Å, a= 80.115 (4), b= 70.479 (4), g= 65.779 (4) and Z= 2. The NiII ion is coordinated by a deprotonated N atom and the carboxylate O atom of the orotate ligand and four aqua ligands in a distorted octahedral geometry. Intermolecular N–H· O and O–H· O hydrogen bonds produce R2 2 (8), R2 2 (12), R2 2 (16), R3 2 (8), R4 3 (8) and R4 4 (12) rings, which lead to a one-dimensional polymeric chains. An extensive three-dimensional network of N–H· O and O–H· O hydrogen bonds, p-p and N–H· p interactions are responsible for crystal stabilization. |
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| Google Scholar | 1 |