Transition metal II complexes of vitamin B13 with monodentate orotate 1 ligands
Yazarlar (4)
Prof. Dr. Dursun Ali Köse Hacettepe Üniversitesi, Türkiye
Birgül Zümreoglu-Karan
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Ondokuz Mayis University Faculty Of Science And Arts, Türkiye
Orhan Büyükgüngör Ondokuz Mayis University Faculty Of Science And Arts, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2006) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2006 |
| Cilt / Sayı / Sayfa | 789 / 1 / 147–151 | DOI | 10.1016/j.molstruc.2005.12.030 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0022286006000305 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The formation of bisorotate(1−) complexes of the type [M(C5H3N2O4)2(H2O)4]·nH2O (M=Co, Ni, Zn and n=2, 4) was achieved by the reaction of ammonium orotate with the corresponding M(II) ions. The crystal structure of [Co(C5H3N2O4)2(H2O)4]·2H2O was determined by single crystal X-ray diffraction analysis. Each Co(II) ion in the monomeric Co(C5H3N2O4)2(H2O)4 units adapts a slightly distorted octahedral geometry comprised of two monodentate orotate anions and four H2O ligands. Columnar packing of pyrimidine rings along the c axis leads to the formation of layers that propagate parallel to the b axis and the adjacent layers are linked by hydrogen bonds forming a 3D lattice. Complexes of nickel and zinc were assumed to contain monodentate bound orotate ligands as well on the basis of physical and spectroscopic data. |
| Anahtar Kelimeler |
| Monodentate coordination | Orotate Complexes | Orotic Acid | Vitamin B13 |
Science Direct
Transition metal II complexes of vitamin B13 with monodentate orotate 1 ligands
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 34 |
| Scopus | 34 |
| Google Scholar | 22 |