Silver Palladium and Rhodium Complexes of Acenaphthylene AnullatedN Heterocyclic Carbene Ligands A Comparative Study
Yazarlar (4)
Hayati Türkmen Ege Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Ondokuz Mayis Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
Bekir Çetinkaya Ege Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | European Journal of Inorganic Chemistry (Q2) | ||
| Dergi ISSN | 1434-1948 Dergi Bilgileri (2006) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2006 |
| Cilt / Sayı / Sayfa | 2006 / 23 / 4915–4921 | DOI | 10.1002/ejic.200600545 |
| Makale Linki | http://doi.wiley.com/10.1002/ejic.200600545 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The newly prepared carbene precursor 1,3‐dimesitylacenaphtho[1,2‐d]imidazolinium chloride, (NHC–H)Cl, 3, could be readily converted into the NHC‐silver(I) complex, 4, which is an efficient carbene transfer agent and has been used to synthesise thione 5, trans‐[PdCl2(NHC)2], 6 and [RhCl(NHC)(COD)], 7. All compounds synthesised were characterised by elemental analysis, NMR spectroscopy and the molecular structures of the thione 5 and complex 7 were determined by X‐ray crystallography. Complex 7 was converted into cis‐[RhCl(NHC)(CO)2] and the electron donating properties and trans influence of the NHC ligand were compared with nonanullated counterparts. The catalytic activity in the Heck reaction of 6 and the in situ formed palladium complex was evaluated. The activity of the in situ formed complexes for the Heck coupling of alkenes was high. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 … |
| Anahtar Kelimeler |
| C-C coupling | N-heterocyclic carbenes | Palladium complexes | Rhodium complexes | Silver complexes | Thiones |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 47 |
| Scopus | 47 |
| Google Scholar | 46 |