Hydrothermal synthesis structural investigation and magnetic properties of 2 D layered lanthanide Ln Pr Eu Gd Tb and Er coordination polymers possessing infinite 1 D nanosized Cavities
Yazarlar (4)
Shahzad Sharif
Lahore College For Women University, Pakistan
Lahore College For Women University, Pakistan
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Bushra Khan
Lahore College For Women University, Pakistan
Lahore College For Women University, Pakistan
Islam Ullah Khan
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Coordination Chemistry (Q3) | ||
| Dergi ISSN | 0095-8972 Dergi Bilgileri (2015) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2015 |
| Cilt / Sayı / Sayfa | 68 / 15 / 2725–2738 | DOI | 10.1080/00958972.2015.1056739 |
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Five 2-D Ln(III) coordination polymers, [Ln(PDA)(PDAH)]n (PDA = 2,6-pyridinedicarboxylate), have been obtained under mild hydrothermal condition. In each coordination polymer, PDA is tetradentate and pentadentate, while lanthanides have coordination number eight to generate trigonal prismatic, triangular face bicapped LnO6N2 geometry having 9 triangular and 2 square faces. Two different types of bridging oxygens are responsible to grow the 2-D coordination polymers providing open channels possessing infinite 1-D nanosized cavities. Adjacent 2-D chains are further extended to a 3-D hydrogen-bonded layered network through intermolecular π–π interactions and C–H⋯O hydrogen bonds. Four lanthanides are arranged roughly at the vertices of a square and bridged by eight carboxylates leading to the overall tetrahedral shape of the secondary building units. The abnormal behavior of lanthanide … |
| Anahtar Kelimeler |
| 2D coordination polymer | Lanthanide | Nanosized | Pyridine-2,6-dicarboxylic acid | Sodium azide |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 11 |
| Scopus | 12 |
| Google Scholar | 15 |