N Alkylation and N C Dialkylation of Amines with Alcohols in the Presence of Ruthenium Catalysts with Chelating N Heterocyclic Carbene Ligands
Yazarlar (7)
Dr. Öğr. Üyesi Zeynel Şahin Inönü Üniversitesi, Türkiye
Prof. Dr. Nevin Gürbüz Inönü Üniversitesi, Türkiye
Prof. Dr. Ismail Özdemir Inönü Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
Mathieu Achard
Institut Des Sciences Chimiques De Rennes, Fransa
Institut Des Sciences Chimiques De Rennes, Fransa
Christian Bruneau
Institut Des Sciences Chimiques De Rennes, Fransa
Institut Des Sciences Chimiques De Rennes, Fransa
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Organometallics (Q1) | ||
| Dergi ISSN | 0276-7333 Dergi Bilgileri (2015) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 06-2015 |
| Cilt / Sayı / Sayfa | 34 / 11 / 2296–2304 | DOI | 10.1021/om501066n |
| Makale Linki | http://pubs.acs.org/doi/abs/10.1021/om501066n | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| A series of new benzimidazolium salts and ruthenium(II) complexes containing chelating N-heterocyclic carbenes (NHCs) functionalized with a benzylic group and an acetal group were prepared. All of the synthesized compounds were characterized by elemental analysis and NMR spectroscopy, and the molecular structures of 2c and 2d were determined by X-ray crystallography. All of the complexes were tested in the alkylation of cyclic amine derivatives with alcohols and showed excellent activity in this reaction. Cyclic amines were alkylated with primary and heteroaromatic alcohols. The Ru–NHC complexes also catalyzed N,C3-dialkylation of cyclic amines. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 54 |
| Scopus | 59 |
| Google Scholar | 63 |