Novel ruthenium II N heterocyclic carbene complexes synthesis characterization and catalytic application
Yazarlar (6)
Prof. Dr. Sedat Yaşar Inönü Üniversitesi, Türkiye
Emine Özge Karaca Inönü Üniversitesi, Türkiye
Çaʇlar Şahin
Zonguldak Bulent Ecevit University, Türkiye
Prof. Dr. Ismail Özdemir Inönü Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Organometallic Chemistry (Q2)
Dergi ISSN 0022-328X Dergi Bilgileri (2015)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 08-2015
Cilt / Sayı / Sayfa 789 / 1 / 1–7 DOI 10.1016/j.jorganchem.2015.04.012
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0022328X15002132
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
The synthesis of highly active ruthenium(II) catalyst based on N-heterocyclic carbene (NHC) bearing alkyl and aryl groups is reported. The complexes are easily handled in very good yields via synthesis of silver–NHC complexes and subsequent reaction with [RuCl2(p-cymene)]2 in dichloromethane (DCM) under N2 condition. All new compounds were characterized by LC-MSMS, elemental analysis, NMR spectroscopy and X-ray diffraction. With the development of a more efficient catalytic system for transfer hydrogenation of aryl ketones and aldehydes in mind, the catalytic performance of the Ru–NHC complexes for transfer hydrogenation was investigated.
Anahtar Kelimeler
N-heterocyclic carbene | Ruthenium-NHC complex | Silver | Transfer hydrogenation reaction
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 35
Scopus 37
Google Scholar 38
Novel ruthenium II N heterocyclic carbene complexes synthesis characterization and catalytic application

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