Dinuclear zinc II complex with tris 2 aminoethyl amine ligand synthesis structure and properties
Yazarlar (5)
Güneş Süheyla Kürkçüoʇlu
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Dr. Öğr. Üyesi Elvan Sayin Eskişehir Osmangazi Üniversitesi, Türkiye
Orhan Büyükgüngör Ondokuz Mayis University Faculty Of Science And Arts, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Zeitschrift Fur Kristallographie Crystalline Materials (Q2) | ||
| Dergi ISSN | 2194-4946 Dergi Bilgileri (2015) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2015 |
| Cilt / Sayı / Sayfa | 230 / 6 / 407–412 | DOI | 10.1515/zkri-2014-1814 |
| Makale Linki | http://www.degruyter.com/view/j/zkri.2015.230.issue-6/zkri-2014-1814/zkri-2014-1814.xml | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The dinuclear complex tris(2-aminoethyl)aminezinc(II)-μ-cyanothreecyanozincate(II) hemihydrate, [Zn(tren)Zn(μ-CN)(CN)3]·0.5H2O (1) (tren = tris(2-aminoethyl)amine), has been synthesized and characterized by spectral (FT-IR and Raman), elemental, thermal analysis (TG, DTG and DTA) as well as single crystal X-ray diffraction techniques. The asymmetric unit is composed of two Zn(II) ions, one tren ligand, four cyanide ligands and a half crystal water molecule which is situated at the special position. Zn1 ion exhibits tetrahedral coordination geometry with four carbon atoms of four cyanide ligands. Zn2 ion is five-coordinated by five nitrogen atoms from one tren and one cyanide ligands in a trigonal bipyramid coordination geometry. The cyanide nitrogen is in the axial position. Adjacent dinuclear units are connected by hydrogen bonding interactions to form three dimensional network. The decomposition reaction … |
| Anahtar Kelimeler |
| Cyanide complex | Dinuclear complex | Tetracyanozincate(II) | Tris(2-aminoethyl)amine | Zinc(II) complex |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 6 |
| Scopus | 6 |
| Google Scholar | 6 |