The syntheses crystal structures spectroscopic and thermal characterization of new pyridine 2 5 dicarboxylate compounds
Yazarlar (5)
Deniz Doʇan
Dumlupinar Üniversitesi, Türkiye
Prof. Dr. Alper Tolga Çolak Dumlupinar Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Tuncay Tunç Aksaray Science Education Department, Türkiye
Öğr. Gör. Ömer Çelik Dicle Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polyhedron (Q2)
Dergi ISSN 0277-5387 Dergi Bilgileri (2015)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 06-2015
Cilt / Sayı / Sayfa 93 / 1 / 37–45 DOI 10.1016/j.poly.2015.03.033
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0277538715001710
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
In this study, four new M(II)-isocinchomeronic acid (pyridine-2,5-dicarboxylic acid) complexes with ethylenediamine (en) and 2,2′-bipyridine (bipy), namely [Co(en)3][Co(pydc)2(H2O)2]·2H2O (1), [Ni(Hpydc)2(H2O)2] (2), [Cu(en)2(H2O)][Cu3(pydc)4(en)2(H2O)2]·3H2O (3) and [Cu(bipy)3][Cu(pydc)(bipy)2]·2Cl·12H2O (4) (H2pydc = pyridine-2,5-dicarboxylic acid), have been synthesised. Elemental, thermal analyses and IR spectroscopic studies have been carried out in order to characterise the complexes. The molecular structures of the complexes have been determined using single crystal X-ray diffraction. The geometry displayed by the Co(II) (1) and Ni(II) (2) ions is distorted octahedral. The Cu(II) ions display a square pyramidal geometry and distorted octahedral geometry in 3, while each Cu(II) ion exhibits a distorted octahedral geometry in 4. Molecules of each complex are linked into a 3D framework structure …
Anahtar Kelimeler
2,2′-Bipyridine | Ethylenediamine | Hydrothermal synthesis | Isocinchomeronic acid | Supramolecular complexes
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 14
Scopus 10
Google Scholar 17
The syntheses crystal structures spectroscopic and thermal characterization of new pyridine 2 5 dicarboxylate compounds

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