Syntheses crystal structures spectroscopic and thermal characterisations of new homophthalate compounds
Yazarlar (5)
Oʇuzhan Orhan
Dumlupinar Üniversitesi, Türkiye
Prof. Dr. Alper Tolga Çolak Dumlupinar Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Tuncay Tunç Aksaray Science Education Department, Türkiye
Öğr. Gör. Ömer Çelik Dicle Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polyhedron (Q2)
Dergi ISSN 0277-5387 Dergi Bilgileri (2015)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 02-2015
Cilt / Sayı / Sayfa 87 / 1 / 268–274 DOI 10.1016/j.poly.2014.11.028
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S027753871400744X
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
In this study, four new M(II)-homophthalate complexes with 2,2′-bipyridine (bipy), N,N-dimethylethylenediamine (dmen), imidazole (im) and 1,10-phenanthroline (phen), namely [Mn(hmph)(bipy)(H2O)2]n (1), [Ni(hmph)(dmen)2(H2O)]·H2O (2), [Cu(hmph)(im)2]n (3) and [Cu(phen)2Cl]·(Hhmph)·(H2hmph) (4) (H2hmph = homophthalic acid) have been synthesised. Elemental and thermal analyses and IR spectroscopic studies have been performed to characterise the complexes. The molecular structures of the complexes have been determined by single crystal X-ray diffraction. The geometries around the Mn(II) (1) and Ni(II) (2) ions are distorted octahedrons. Each Cu(II) ion exhibits penta-coordination with a distorted square-pyramidal geometry in 3 and a distorted trigonal–bipyramidal geometry in 4. In 1 and 3, hmph is a bridging ligand that forms 1D and 2D coordination polymers, which are extended into 3D layers …
Anahtar Kelimeler
Bipyridine | Homophthalate 2,2′ | Imidazole | N,N-dimethylethylenediamine 1,10-Phenanthroline
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 4
Scopus 2
Google Scholar 3
Syntheses crystal structures spectroscopic and thermal characterisations of new homophthalate compounds

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