Gas adsorption separationpropertiesofmetaldirectedself assemblyof twocoordinationpolymerswith5 nitroisophthalate
Yazarlar (4)
Prof. Dr. Mürsel Arici Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Doç. Dr. Seda Keskin Koç University, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Solid State Chemistry (Q2) | ||
| Dergi ISSN | 0022-4596 Dergi Bilgileri (2014) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2014 |
| Cilt / Sayı / Sayfa | 210 / 1 / 280–286 | DOI | 10.1016/j.jssc.2013.11.010 |
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
|
||
| Özet |
| Two new coordination polymers, namely, [Co(µ-nip)(µ-bpe)]n (1) and [Zn(µ-nip)(µ-bpe)]n (2) (nip: 5-nitroisophthalate, bpe: 1,2-bis(4-pyridyl)ethane) were hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, IR spectroscopy, elemental analysis and thermal analysis. Moreover, atomically detailed simulation studies of complex 2 for CO2/CH4 adsorption and separation were performed. Complex 1 consists of two dimensional (2D) (4,4) grid networks with the point symbol of 44.62. Complex 2 exhibits a 3-fold interpenetrating 3D framework with 65.8-dmp topology. Thermal properties of the complexes showed that both complexes were stable over 320 °C. Simulation studies demonstrated that complex 2 can separate CO2 from CH4 at low pressures at 273 K. |
| Anahtar Kelimeler |
| 5-Nitroisophthalate | Coordination polymer | Molecular simulations |
Science Direct
Gas adsorption separationpropertiesofmetaldirectedself assemblyof twocoordinationpolymerswith5 nitroisophthalate
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 16 |
| Scopus | 17 |
| Google Scholar | 22 |