Dinuclear and polynuclear copper II complexes with3 30 thiodipropionate and unprecedented coordination mode
Yazarlar (4)
Prof. Dr. Mürsel Arıcı Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Murat Taş Giresun Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q2) | ||
| Dergi ISSN | 0277-5387 Dergi Bilgileri (2014) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2014 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-03-2014 |
| Cilt / Sayı / Sayfa | 71 / 1 / 62–68 | DOI | 10.1016/j.poly.2014.01.005 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S0277538714000138 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Three new coordination compounds, {[Cu(μ3-tdp)(phen)]·2H2O}n (1), {[Cu(μ3-tdp)(bipy)]·H2O}n (2), [Cu2(μ2-tdp)(phen)4](NO3)2·2H2O (3) [tdpH2 = 3,3′-thiodipropionic acid, phen = 1,10-phenanthroline, bipy = 2,2′-bipyridine] were synthesized and characterized by the IR spectroscopy, elemental analysis, magnetic measurements and single crystal X-ray diffraction. Thermal behaviors and thermochromic properties of the complexes were investigated in detail. Complexes 1 and 2 are 1D coordination polymers while complex 3 is dinuclear structure. In complexes 1 and 2, the tdp acts as a tridentate bridging ligand to coordinate the two different Cu(II) centers to form 1D chain, which are extended into a 3D networks by hydrogen bonding and π⋯π interactions. The 3,3′-thiodipropionate ligand adopts a new coordination mode in 3. Furthermore, complex 3 changed the color from blue to green at 140 °C at solid state. |
| Anahtar Kelimeler |
| 3,3′-Thiodipropionate complexes | Coordination polymers | Copper(II) complexes | Dinuclear complex | Thermochromism |
Science Direct
Dinuclear and polynuclear copper II complexes with3 30 thiodipropionate and unprecedented coordination mode
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 7 |
| Scopus | 7 |
| Google Scholar | 7 |