Boric acid complexes with thiamine vitamin B1 and pyridoxine vitamin B6
Yazarlar (4)
Prof. Dr. Dursun Ali Köse Hitit University, Türkiye
Birgül Zumreoglu-Karan
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Inorganica Chimica Acta (Q2) | ||
| Dergi ISSN | 0020-1693 Dergi Bilgileri (2014) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2014 |
| Cilt / Sayı / Sayfa | 413 / 1 / 77–83 | DOI | 10.1016/j.ica.2013.12.045 |
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Complexation of boric acid with vitamins B1 (thiamine) and B6 (pyridoxine) was investigated. The products were isolated from aqueous solutions and characterized by elemental analysis, FT-IR, 13C MAS NMR and thermal methods. The results of chemical and spectral analyses suggested that the reaction between thiaminechloride hydrochloride and H3BO3 in water yielded a salt-like productwith no direct bonding of the thiamine cation to boron while mono- and bis-chelate complexes were obtained with pyridoxine. The bis-chelate pyridoxine complex containing two equivalent pyridoxine ligands was obtained in crystal form. X-ray crystallography verified that complexation with boric acid occurs through the deprotonated phenolic and deprotonated adjacent alcoholic oxygen atoms forming six membered chelate rings. The negative charge on tetrahedral boron is balanced by the sodium ion. The crystal structure … |
| Anahtar Kelimeler |
| Borate ester | Boric acid | Boron chelate | Crystal structure | Pyridoxine | Thiamine |
Science Direct
Boric acid complexes with thiamine vitamin B1 and pyridoxine vitamin B6
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 26 |
| Scopus | 25 |
| Google Scholar | 34 |