One pot synthesis of two new metal organic networks hydrogen bonded mononuclear Cu II complex and mixed valence Cu I II coordination polymer with encapsulated 14 membered unique water cluster
Yazarlar (4)
Fatih Semerci Kirklareli Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Fatma Yüksel Gebze Teknik Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Inorganic Chemistry Communications (Q2) | ||
| Dergi ISSN | 1387-7003 Dergi Bilgileri (2015) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2015 |
| Cilt / Sayı / Sayfa | 62 / 1 / 29–33 | DOI | 10.1016/j.inoche.2015.10.016 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S1387700315301076 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
|
||
| Özet |
| {[Cu4(μ-bpe)4Cu2(μ-pydc)2(μ3-pydc)2]·14H2O}n (1) and [Cu(pydcH)2(bpe)2] (2) have been solvothermally synthesized by 1,2-bis(4-pyridyl)ethylene (bpe) along with dianionic pyridine-2,3-dicarboxylate (pydc) ligands and characterized by elemental, FT-IR and thermal analyses techniques. In the solvothermal synthesis of complexes, 1 was isolated when the reactor was opened whereas 2 was crystallized after 3 weeks. The X-ray crystallographic studies show that complex 1 exhibits ladder-like structure involving mixed-valence Cu(I,II) which has generated a simultaneous in situ redox reaction and a unique 14-membered water cluster consisting of an eight-membered open-cube hexamer and two cyclic water trimers has been observed in hydrophilic cavities of 1. Supramolecular network of 2, which has proton transfer product of pydcH cations, is formed by O–H···N and aromatic interactions. |
| Anahtar Kelimeler |
| 1,2-bis(4-pyridyl)ethylene | Coordination polymers | Mixed-valence Cu(I, II) | One-pot synthesis | Pyridine-2,3-dicarboxylate | Solvothermal synthesis | Water clusters |
Science Direct
One pot synthesis of two new metal organic networks hydrogen bonded mononuclear Cu II complex and mixed valence Cu I II coordination polymer with encapsulated 14 membered unique water cluster
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 9 |
| Scopus | 10 |
| Google Scholar | 11 |