Seven eight and ten coordinated cerium III with highlyconnective pyridine 2 4 6 tricarboxylate oxalate and glycineligands
Yazarlar (3)
Islam Ullah Khan
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Shahzad Sharif
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Coordination Chemistry (Q2) | ||
| Dergi ISSN | 0095-8972 Dergi Bilgileri (2013) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2013 |
| Cilt / Sayı / Sayfa | 66 / 17 / 3113–3125 | DOI | 10.1080/00958972.2013.825719 |
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Two new 3-D Ce(III) coordination polymers, [Ce1.3(PTA)2(Oxa)2(Gly)(H2O)2]·(Gly)4H2O (1) and [Ce2.6(PTA)4(Oxa)2(H2O)10]·(MeOH)7H2O (2) (PTA = 2,4,6-pyridinetricarboxylate, oxa = oxalate and Gly = glycine), were synthesized. The oxalate in 1 and 2, generated in situ from the cleavage and chemical rearrangement of PTAH3, assembled into mixed-ligand networks to generate 3-D frameworks. Single crystal analysis reveals that in both complexes, Ce(III) shows coordination numbers of 7 and 10 in 1 and 8 and 10 in 2. PTA adopts four kinds of coordination modes. These complexes were further characterized using elemental analysis, FTIR spectroscopy and thermogravimetric analysis. |
| Anahtar Kelimeler |
| Pyridine-2,4,6-tricarboxylic acid |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 8 |
| Scopus | 8 |
| Google Scholar | 8 |