The synthesis characterization and theoretical hydrogen gasadsorption properties of copper II 3 3 thiodipropionatecomplexes with imidazole derivatives
Yazarlar (5)
Prof. Dr. Mürsel Arıcı Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Seda Keskin Avcı Koç Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayıs Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı JOURNAL OF COORDINATION CHEMISTRY (Q2)
Dergi ISSN 0095-8972 Dergi Bilgileri (2013)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 12-2013
Kabul Tarihi Yayınlanma Tarihi 04-12-2013
Cilt / Sayı / Sayfa 66 / 23 / 4093–4106 DOI 10.1080/00958972.2013.860223
Makale Linki https://www.tandfonline.com/doi/full/10.1080/00958972.2013.860223
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
Three new coordination polymers, [Cu(μ3-tdp)(im)2]n (1), {[Cu(μ3-tdp)(1-mim)2]·0.5H2O}n (2) and {[Cu2(μ3-tdp)2(4-mim)4]·H2O}n (3) [tdpH2 = 3,3′-thiodipropionic acid, im = imidazole, 1-mim = 1-methylimidazole and 4-mim = 4-methylimidazole], have been prepared and characterized by spectroscopic techniques (IR and UV–Vis), elemental analyzes, magnetic measurements, thermal analyzes, and single-crystal X-ray diffraction. Complexes 1–3 crystallize in the monoclinic system with space groups of C2/c and P21/c, respectively. In 1–3, tdp is a bridging ligand to form 1-D chains, which are extended into a 2-D layer by hydrogen bonding and π···π interactions. The 3,3′-thiodipropionate exhibits an unexpected coordination mode in 1–3. Simulations were used to assess the potential of the complexes in H2 storage applications.
Anahtar Kelimeler
33-Thiodipropionic acid | 33-Thiodipropionate complexes | Imidazole complexes | Copper(II) complexes