Synthesis crystal structure and catalytic activity for H2O2 disproportionation of the manganese II coordination polymer Mn O2C CF2 8CO2 phen 2 H2O n phen 1 10 phenanthroline
Yazarlar (4)
Prof. Dr. Ibrahim Kani Anadolu Üniversitesi, Türkiye
Canan Darak
Anadolu Üniversitesi, Türkiye
Anadolu Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Ondokuz Mayis Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q2) | ||
| Dergi ISSN | 0277-5387 Dergi Bilgileri (2008) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2008 |
| Cilt / Sayı / Sayfa | 27 / 4 / 1238–1247 | DOI | 10.1016/j.poly.2007.12.032 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0277538708000041 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The title polymeric complex {[Mn(O2C(CF2)8CO2)(phen)2]H2O}n was synthesized through the reaction of 1,10-phenanthroline, perfluorosebacic acid and MnCO3·H2O. The molecular structure was characterized by X-ray diffraction, elemental analysis, thermal gravimetry, IR and UV–Vis spectroscopy and its catalytic activity has been studied. X-ray structure analysis shows that each Mn(II) ion is octahedrally coordinated by two bidentate phenanthroline ligands and the carboxylate oxygen atoms from two symmetry related perfluorosebacate ligands, which are coordinated in cisoid positions. The structure consists of polymeric chains, with the perfluorosebacato ligand bridging the Mn(II) ions in a monodentate fashion. Crystallographic characterization shows a supramolecular structure involving hydrogen bonds, π–π and π-ring interactions. The catalytic results indicated that the complex has reasonably good activity … |
| Anahtar Kelimeler |
| 1,10-Phenanthroline | Catalysis | Disproportionation | Hydrogen peroxide | Manganese | Perfluorosebacic acid |
Science Direct
Synthesis crystal structure and catalytic activity for H2O2 disproportionation of the manganese II coordination polymer Mn O2C CF2 8CO2 phen 2 H2O n phen 1 10 phenanthroline
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 17 |
| Scopus | 16 |
| Google Scholar | 18 |