Palladium N heterocyclic carbene complexes Synthesis characterization and catalytic properties in amination
Yazarlar (5)
Prof. Dr. Ismail Özdemir Inönü Üniversitesi, Türkiye
Öğr. Gör. Serpil Demir Inönü Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Ondokuz Mayis Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
Bekir Çetinkaya Ege Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Organometallic Chemistry (Q2) | ||
| Dergi ISSN | 0022-328X Dergi Bilgileri (2010) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2010 |
| Cilt / Sayı / Sayfa | 695 / 10 / 1555–1560 | DOI | 10.1016/j.jorganchem.2010.03.013 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0022328X1000152X | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Transmetalation has proved to be a promising procedure to obtain NHC–metal complexes, which typically involves treatment of the imidazolium salt with Ag2O to form the Ag–NHC complex, followed by transmetalation to a species such as [PdCl2(CH3CN)2] gave the palladium complex in which the N-heterocyclic carbene was bound to the metal center. New bis(NHC)–Pd complexes were synthesized and characterized by elemental analysis, 1H NMR, 13C NMR, and IR spectroscopy. The crystal and molecular structure of the trans-dichlorobis{1-(2,3,5,6-tetramethylbenzyl)-3-(2,3,4,5,6-pentamethylbenzyl)imidazolidin-2-yliden}palladium(II) complex was determined by single-crystal X-ray diffraction. The activity of the Pd(II) complexes in the coupling reaction of anilines or amines with bromobenzene was investigated. A preliminary catalytic study showed that these bis(NHC)–Pd complexes were highly active in the … |
| Anahtar Kelimeler |
| Amination | Amines | N-heterocyclic carbene | Palladium catalysis | Triarylamines |
Science Direct
Palladium N heterocyclic carbene complexes Synthesis characterization and catalytic properties in amination
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 21 |
| Scopus | 22 |
| Google Scholar | 29 |