C H Pd interactions and cyano bridged heteronuclear polymeric complexes
Yazarlar (5)
Lkay Ayli Eskişehir Osmangazi Üniversitesi, Türkiye
Güne Süheyla Kürküolu
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Okan Zafer Yeilel
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Ondokuz Mayis University Faculty of Science And Arts, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis University Faculty of Science And Arts, Türkiye
Ondokuz Mayis University Faculty of Science And Arts, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q2) | ||
| Dergi ISSN | 0277-5387 Dergi Bilgileri (2012) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2012 |
| Cilt / Sayı / Sayfa | 31 / 1 / 386–394 | DOI | 10.1016/j.poly.2011.09.030 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0277538711005948 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Three new heterometallic complexes, [Cu(N-Meim)4Pd(μ-CN)2(CN)2]n (1), [Zn(N-Meim)3Pd(μ-CN)2(CN)2]n (2) and [Cd(N-Meim)2Pd(μ-CN)4]n (3), have been isolated from the reactions of M[Pd(CN)4] (M=Cu(II), Zn(II) or Cd(II)) and N-Meim (N-methylimidazole) with in different molar ratios. All complexes have been characterized by X-ray analyses, vibrational (FT-IR and Raman) spectra, thermal and elemental analyses. The crystallographic analysis reveals that the crystal structures of 1 and 2 are 1D coordination polymer, while 3 presents a 2D network. In the Cu(II) and Zn(II) complexes, two cyanide groups of [Pd(CN)4]2− coordinated to the adjacent M(II) ions and distorted octahedral and square pyramidal geometries of complexes are completed by four and three nitrogen atoms of N-Meim ligands, respectively. The Cd(II) ion is six-coordinate, completed with the two nitrogen atoms of N-Meim ligands in the axial … |
| Anahtar Kelimeler |
| Heteronuclear polymeric complexes | Intermolecular C-H⋯Pd interactions | N-methylimidazole complexes | Tetracyanopalladate(II) complexes | Vibrational spectra |
Science Direct
C H Pd interactions and cyano bridged heteronuclear polymeric complexes
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 20 |
| Scopus | 14 |
| Google Scholar | 22 |