Structural spectral electrochemical and catalytic reactivity studies of a seriesof N2O2 chelated palladium II complexes
Yazarlar (5)
Mahmut Ulusoy
Harran Üniversitesi, Türkiye
Özgül Birel
Muğla Sıtkı Koçman Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Ondokuz Mayis Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Türkiye
Bekir Cetinkaya
Ege Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polyhedron (Q2)
Dergi ISSN 0277-5387 Dergi Bilgileri (2012)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2012
Cilt / Sayı / Sayfa 38 / 1 / 141–148 DOI 10.1016/j.poly.2012.02.035
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
A series of neutral salicylaldiminato Pd(II) complexes have been synthesized and characterized. Spectral and electrochemical properties of the complexes in the solution phase have been investigated. The structure of complex 9 has been confirmed by X-ray analysis. Spectroscopic characteristics were determined by visible absorption spectra. Cyclic voltammetry analysis has been performed to determine the energy levels of the compounds. The coordination of the Schiff base, according to the spectroscopic techniques, appears to occur through the two azomethine nitrogens and two o-OH groups. The salen type Pd(II) complexes have been used as catalysts for the formation of cyclic organic carbonates from carbon dioxide and liquid epoxides, which served as both reactant and solvent. The more electron donating substituents on the backbone and the aryl ring of the ligand system, in particular, effectively promote …
Anahtar Kelimeler
Carbon dioxide | Catalysis | Cyclic carbonate | Pd(II) complex
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 26
Scopus 29
Google Scholar 34
Structural spectral electrochemical and catalytic reactivity studies of a seriesof N2O2 chelated palladium II complexes

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