1 D and 2 D coordination polymers of cerium III with pyridine 2 4 6 tricarboxylic acid synthesis and structural spectroscopic and thermal properties
Yazarlar (4)
Shahzad Sharif
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Prof. Dr. Onur ŞAHİN Ondokuz Mayis University Faculty Of Science And Arts, Türkiye
Islam Ullah Khan
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Orhan Büyükgngr Ondokuz Mayis University Faculty Of Science And Arts, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Coordination Chemistry (Q2) | ||
| Dergi ISSN | 0095-8972 Dergi Bilgileri (2012) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 06-2012 |
| Cilt / Sayı / Sayfa | 65 / 11 / 1892–1904 | DOI | 10.1080/00958972.2012.685165 |
| Makale Linki | http://www.tandfonline.com/doi/abs/10.1080/00958972.2012.685165 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Two new Ce(III) complexes of pyridine-2,4,6-tricarboxylate (ptc), [Ce2(H2O)2(C8H3NO6)4(C2O4)Na2(H2O)5] n (H2O)4 (1) and [Ce(H2O)3(C8H2NO6)] n (H2O) (2), were crystallized in the triclinic space group P-1 and the monoclinic space group P21 /c, respectively. These polymers were also characterized by elemental analysis, FTIR spectroscopy, and thermogravimetric analysis. The latter shows high thermal stability for 1. Each Ce(III) is ten-coordinate with two nitrogen atoms from two pyridine rings, five oxygen atoms from five carboxylic groups, two oxygen atoms from oxalate and one oxygen from water. Oxygen at the 2,6-position of ptc is a bridge to construct a 1-D polymer for 1. Each Ce(III) is nine-coordinate with five oxygen atoms and one nitrogen from ptc and three water molecules, giving a tricapped trigonal prism for 2. Each ptc bridges three Ce(III) ions with the formation of 2-D polymeric chains, and each … |
| Anahtar Kelimeler |
| 2-D lanthanide polymers | Cerium(III) | Hydrogen bonds | Pyridine-2,4,6-tricarboxylic acid |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 21 |
| Scopus | 22 |
| Google Scholar | 21 |