Synthesis and Crystal Structures of a Lanthanum III 1D Polymer and a Mixed Ligand Cerium III Binuclear Complex Derived from Pyridine 2 6 dicaboxylic Acid
Yazarlar (6)
Shahzad Sharif
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Islam Ullah Khan
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Prof. Dr. Onur ŞAHİN Ondokuz Mayis University Faculty Of Science And Arts, Türkiye
Saeed Ahmad
University Of Engineering And Technology, Lahore, Pakistan
University Of Engineering And Technology, Lahore, Pakistan
Orhan Büyükgüngör Ondokuz Mayis University Faculty Of Science And Arts, Türkiye
Salamat Ali
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Inorganic and Organometallic Polymers and Materials (Q2) | ||
| Dergi ISSN | 1574-1443 Dergi Bilgileri (2012) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2012 |
| Cilt / Sayı / Sayfa | 22 / 5 / 1165–1173 | DOI | 10.1007/s10904-012-9715-7 |
| Makale Linki | http://link.springer.com/10.1007/s10904-012-9715-7 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Lanthanum(III) and cerium(III) complexes of pyridine-2,6-dicaboxylic acid (H2Pydc) have been prepared and their crystal structures were determined by X-ray crystallography. The single crystal analysis reveals that the lanthanum(III) complex, 1 is polymeric consisting of {[La(Pydc)2(H2O)2]·4H2O}n units linked through carboxylate oxygen atoms and exhibiting nine coordination number. Intermolecular O–H···O hydrogen bonds produce R11(6), R44(16) and R44(20) rings, which lead to three-dimensional polymeric chains. The crystal structure of the cerium(III) complex, 2 [{Ce(Pydc)3}{Ce(Pydc)(HO–CH2CH2–OH)(H2O)3}·6H2O)] shows that the complex is a mixed-ligand binuclear system in which one cerium coordinated to three Pydc molecules, while the other cerium is bound to one Pydc, one oxygen atom of the other Pydc, one ethylene glycol and three water molecules. Each of the two Ce(III) ions is nine … |
| Anahtar Kelimeler |
| Cerium(III) | Ethylene glycol | Hydrogen bonds | Lanthanum(III) | Mixed-ligand | Pyridine-2,6-dicaboxylic acid |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 17 |
| Scopus | 16 |
| Google Scholar | 21 |