Piano stool benzothiazol 2 ylidene Ru II complexes for effective transfer hydrogenation of carbonyls
Yazarlar (6)
Zeynep Ipek Oruç
Ege Üniversitesi, Türkiye
Ege Üniversitesi, Türkiye
Lütfiye Gok Ege Üniversitesi, Türkiye
Prof. Dr. Hayati Türkmen Ege Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayıs Üniversitesi, Türkiye
Ondokuz Mayıs Üniversitesi, Türkiye
Bekir Çetinkaya Ege Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Organometallic Chemistry (Q2) | ||
| Dergi ISSN | 0022-328X Dergi Bilgileri (2016) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2016 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-04-2016 |
| Cilt / Sayı / Sayfa | 807 / 1 / 36–44 | DOI | 10.1016/j.jorganchem.2016.02.003 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0022328X16300365 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Benzothiazolium bromides (NSHC. HBr)(1a-j) with a variety of alkyl chain or benzyl substituents on N atom were prepared. The synthesis of ruthenium (II)(NSHC) complexes,(2a–j) could be achieved by in situ deprotonation of benzothiazolium salts with Ag2 O and [RuCl2(p-cymene)]2. They were characterized by 1H, 13C, 19F NMR, IR spectroscopy and elemental analysis. The molecular structures of 2d, 2e and 2g were ascertained by single-crystal X-ray diffraction studies. The catalytic properties of complexes,(2a–j), with electron-donating or-withdrawing groups were investigated in transfer hydrogenation (TH) of ketones, and aldehydes with good to excellent yields. The presence of the CH2(CH2)16 CH3 or CH2 C6 F5 on the N atom of the benzothiazol-2-ylidene complexes (2g, 2j) showed the highest activity for TH reaction. The catalytic properties of the N-alkyl substituted ruthenium (II)(NSHC) complexes (2h–j) may be interpreted by micelle effects.© 2016 Elsevier BV |
| Anahtar Kelimeler |
| Benzothiazolium salts | Catalysis | NSHC-Ru(II) complexes | The transfer hydrogenation |
Science Direct
Piano stool benzothiazol 2 ylidene Ru II complexes for effective transfer hydrogenation of carbonyls
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 14 |
| Scopus | 16 |
| Google Scholar | 17 |