Synthesis and characterization of new coordination polymers based on 2 3 3 4 pyridinedicarboxylates and bispyridine ligands with structural diversity
Yazarlar (4)
Prof. Dr. Fatih Semerci Kırklareli Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Fatma Yüksel Gebze Teknik Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polyhedron (Q2)
Dergi ISSN 0277-5387 Dergi Bilgileri (2016)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 06-2016
Cilt / Sayı / Sayfa 111 / 1 / 1–10 DOI 10.1016/j.poly.2016.02.040
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0277538716001340
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
New coordination polymers, formulated as {bpaH2[Cu(μ-2,3-pydc)2]}n (1), [Cd(μ-2,3-pydc)(μ-bpa)0.5(H2O)2]n (2), {[Co2(μ4-3,4-pydc)2(μ-bpe)(H2O)2]·H2O}n (3) and [Cu2(pic)4(μ-4,4′-bipy)]·(4,4′-bipy)·2H2O (4) have been synthesized based on the bispyridine ligands; 1,2-bis(4-pyridyl)ethane (bpa), 1,2-bis(4-pyridyl)ethylene (bpe) and 4,4′-bipyridine (4,4′-bipy) along with dianionic 2,3- and 3,4-pyridinedicarboxylate (2,3-pydc and 3,4-pydc) and mono anionic picolinate (pic) ligands, respectively. All the complexes have been characterized by elemental and IR spectroscopy and single-crystal X-ray diffraction studies. 1 has proton transfer products of bpaH2 cations and shows 1D double chain. Using of the 2,3-pydc and 3,4-pydc ligands in 2 and 3 in the presence of Cd(II) and Co(II) ions generate 1D → 2D inclined polycatenated structure in 2 and 4,5 connected {44·62·104}{44·62} 4,5T6 topology in 3 …
Anahtar Kelimeler
1,2-Bis(4-pyridyl)ethane | 1,2-bis(4-pyridyl)ethylene and solvothermal synthesis | Coordination polymers | Pyridine-2,3-dicarboxylate | Pyridine-3,4-dicarboxylate