Synthesis characterization crystal structure redox reactivity and antiproliferative activity studies of Cu II and Pd II complexes with F CF3 bearing 3 5 di tert butylsalicylaldimines
Yazarlar (3)
Veli T. Kasumov
Harran Üniversitesi, Türkiye
Harran Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Hatice Gümüşhan Aktas
Harran Üniversitesi, Türkiye
Harran Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q2) | ||
| Dergi ISSN | 0277-5387 Dergi Bilgileri (2016) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2016 |
| Cilt / Sayı / Sayfa | 115 / 1 / 119–127 | DOI | 10.1016/j.poly.2016.03.061 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0277538716300730 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| In this work, based on 3,5-di-tert-butyl-2-hydroxybenzaldehyde and F, CF3-substituted anilines [2-fluoro-3-(trifluromethyl)aniline, 2-fluoro-5-(trifluromethyl)aniline, 3,5-bis(trifluoromethylaniline and 2-fluoro-3-(trifluromethyl)benzylaniline], the corresponding salicylaldimine ligands (HLx, X = 1, 2, 3, 4) and their CuLx2 and PdLx2 complexes were synthesized. The structures of these compounds were characterized by spectroscopic (IR, UV/Vis, 1H and 19F NMR, ESR) and X-ray diffraction techniques. Chemical oxidation of the tert-buylated HLx ligands and their CuLx2 complexes using Ce(IV) under anaerobic and aerobic conditions at room temperature (r.t.) in DMF solution revealed the generation of phenoxyl radicals. An X-ray structural study revealed that thanks to CH⋯F and CH⋯π bonds both the CuL21 and PdL21 molecules crystallize as hydrated dimers that pack differently. The antiproliferative potentials of all the … |
| Anahtar Kelimeler |
| Antiproliferative activity | CuII-phenoxyl | F,CF3Ph-salicylaldimines | Redox reactivity | X-ray |
Science Direct
Synthesis characterization crystal structure redox reactivity and antiproliferative activity studies of Cu II and Pd II complexes with F CF3 bearing 3 5 di tert butylsalicylaldimines
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| Web of Science | 3 |
| Scopus | 3 |
| Google Scholar | 7 |