One dimensional coordination polymers Synthesis crystal structures and spectroscopic properties
Yazarlar (4)
Doç. Dr. Dursun Karaagaç Ulubatlı Hasan Anatolian High School, Türkiye
Prof. Dr. Günes Süheyla Kürkçüoglu Eskişehir Osmangazi Üniversitesi, Türkiye
Mustafa Şenyel
Anadolu Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q3)
Dergi ISSN 0022-2860 Dergi Bilgileri (2016)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 11-2016
Cilt / Sayı / Sayfa 1123 / 1 / 327–334 DOI 10.1016/j.molstruc.2016.06.036
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0022286016306123
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
Two new one dimensional (1D) cyanide complexes, namely [M(4-aepy)2(H2O)2][Pt(CN)4], (4-aepy = 4-(2-aminoethyl)pyridine M = Cu(II) (1) or Zn(II) (2)), have been synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, single crystal X-ray diffraction, thermal and elemental analyses techniques. The crystallographic analyses reveal that 1 and 2 are isomorphous and isostructural, and crystallize in the monoclinic system and C2 space group. The Pt(II) ions are coordinated by four cyanide-carbon atoms in the square-planar geometry and the [Pt(CN)4]2− ions act as a counter ion. The M(II) ions display an N4O2 coordination sphere with a distorted octahedral geometry, the nitrogen donors belonging to four molecules of the organic 4-aepy that act as unidentate ligands and two oxygen atoms from aqua ligands. The crystal structures of 1 and 2 are similar each other and linked via intermolecular …
Anahtar Kelimeler
4-(2-Aminoethyl)pyridine complex | Copper(II) complex | Crystal structure | Tetracyanoplatinate(II) complex | Vibrational spectra | Zinc(II) complex
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 10
Scopus 10
Google Scholar 10
One dimensional coordination polymers Synthesis crystal structures and spectroscopic properties

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