Diphenic acid nicotinamide and 1 10 phenanthroline complexes of CoII CuII and ZnII Synthesis and structural investigation

ŞAHİN, ZARİFE SİBEL; ŞAHİN, ONUR; Dagli, Ozge; Kose, Dursun Ali

doi:10.1016/j.poly.2016.05.051

Diphenic acid nicotinamide and 1 10 phenanthroline complexes of CoII CuII and ZnII Synthesis and structural investigation

Yazarlar (4)

Prof. Dr. Zarife Sibel ŞAHİN Sinop Üniversitesi, Türkiye

Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye

Arş. Gör. Ozge Dagli Hitit University, Türkiye

Prof. Dr. Dursun Ali Kose Hitit University, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Polyhedron (Q2)
Dergi ISSN	0277-5387 Dergi Bilgileri (2016)
Dergi Tarandığı Indeksler	SCI-Expanded
Makale Dili	İngilizce	Basım Tarihi	10-2016
Cilt / Sayı / Sayfa	117 / 1 / 214–223	DOI	10.1016/j.poly.2016.05.051
Makale Linki	http://linkinghub.elsevier.com/retrieve/pii/S0277538716302042
UAK Araştırma Alanları	Yoğun Madde Fiziği

Özet

The complexes of diphenic acid with Co^II and Cu^II metals and diphenic acid/nicotinamide mixed ligand with Co^II and Zn^II metals were synthesized and characterized of structural properties by elemental analysis, FT-IR spectra, thermo analytic TG-DTG/DTA and crystal X-ray diffraction methods. The pure ligand complexes of diphenic acid (C14H16O8Co (1), C14H16O8Cu (2)) and mixed ligand complexes of diphenic acid/nicotinamide (C40H38N4O14Co (3), C40H38N4O14Zn (4)) are similar to each other and they have P21, P21/n and P1 space groups. The diphenic acid ligands in 1 and 2 complexes were coordinated to metal cations as dianionic bridge and in the others complexes (3 and 4) it was involved as monoanionic counter ion. The complexes of 1 and 2 are linked into sheets by a combination of O-H O hydrogen bonds and the others complexes of 3 and 4 are linked into sheets by a combination of O-H O, N-H O and C-H O hydrogen bonds. All of the complexes structures have distorted octahedral geometry. According to TG/DTG-DTA analysis, thermal decomposition of complexes starts with dehydration of coordinated aqua ligands. After the dehydration, neutral nicotinamide ligands start to decompose in mixed ligand complexes. Lastly, anionic diphenic acid ligands decompose and corresponding metal oxides remain as residual products of thermal degradation in reaction vessel.

Anahtar Kelimeler

Diphenic acid | Energy storage materials | Metal organic materials (MOMs) | Nicotinamide | Thermal analysis

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Web of Science	12
Scopus	12
Google Scholar	4
Google Scholar	15

Diphenic acid nicotinamide and 1 10 phenanthroline complexes of CoII CuII and ZnII Synthesis and structural investigation

Dergi Adı	POLYHEDRON
Kısa Adı	POLYHEDRON
Yayıncı	PERGAMON-ELSEVIER SCIENCE LTD
Açık Erişim	Hayır
ISSN	0277-5387
E-ISSN	1873-3719
Wos Quartile	Q2
Scopus Quartile	Q2
Tarandığı Indeksler	SCIE , Scopus
WoS Kategoriler	CHEMISTRY, INORGANIC & NUCLEAR \| CRYSTALLOGRAPHY
Scopus Kategoriler	MATERIALS CHEMISTRY \| INORGANIC CHEMISTRY \| PHYSICAL AND THEORETICAL CHEMISTRY

Diphenic acid nicotinamide and 1 10 phenanthroline complexes of CoII CuII and ZnII Synthesis and structural investigation

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