Synthesis of palladium complexes derived from imidazolidin 2 ylidene ligands and used for catalytic amination reactions
Yazarlar (5)
Öğr. Gör. Emine Özge Karaca İnönü Üniversitesi, Türkiye
Prof. Dr. Nevin Gürbüz İnönü Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayıs Üniversitesi, Türkiye
Ondokuz Mayıs Üniversitesi, Türkiye
Prof. Dr. İsmail Özdemir İnönü Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Applied Organometallic Chemistry (Q2) | ||
| Dergi ISSN | 0268-2605 Dergi Bilgileri (2016) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2016 |
| Cilt / Sayı / Sayfa | 30 / 12 / 1050–1055 | DOI | 10.1002/aoc.3541 |
| Makale Linki | http://doi.wiley.com/10.1002/aoc.3541 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| N‐Aryl amination and the Buchwald–Hartwig reaction are of great synthetic and industrial interest and scientists accept their usefulness and versatility for obtaining arylamines. In this study Ag–N‐heterocyclic carbene complexes were used as transmetallation reagents for the synthesis of Pd–N‐heterocyclic carbene complexes. The new Pd–N‐heterocyclic carbene complexes were characterized using elemental analysis and 1H NMR, 13C NMR and infrared spectroscopies. The crystal structure of one, namely dichlorobis[1,3‐bis(2‐methylbenzyl)imidazolidin‐2‐yliden]palladium(II), is presented. The activity of the Pd(II) complexes in the coupling reaction of anilines or amines with bromobenzene was investigated. These complexes exhibited high catalytic activities in the direct synthesis of triarylamines and secondary amines in a single step. Copyright © 2016 John Wiley & Sons, Ltd. |
| Anahtar Kelimeler |
| amination | imidazolidin-2-ylidene | N-heterocyclic carbene | palladium |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 8 |
| Scopus | 7 |
| Google Scholar | 7 |