One dimensional coordination polymers with 4 2 aminoethyl pyridine Synthesis crystal structures and spectroscopic properties
Yazarlar (5)
Doç. Dr. Dursun Karaağaç Ulubatlı Hasan Anatolian High School, Türkiye
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Mustafa Şenyel
Anadolu Üniversitesi, Türkiye
Anadolu Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q2) | ||
| Dergi ISSN | 0277-5387 Dergi Bilgileri (2017) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2017 |
| Cilt / Sayı / Sayfa | 123 / 1 / 56–61 | DOI | 10.1016/j.poly.2016.10.046 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0277538716305435 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Two new one-dimensional polymeric metal complexes, namely [Zn(NH3)(μ-4aepy)Ni(μ-CN)(CN)3]n (1) and [Cu(H2O)(μ-4aepy)Pd(μ-CN)(CN)3]n (2) [4aepy = 4-(2-aminoethyl)pyridine], were synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, single crystal X-ray diffraction, thermal and elemental analyses techniques. The complexes crystallize in the monoclinic system, P21/n space group. The asymmetric units of 1 and 2 contain two M(II) ions [M = Zn(II) and Ni(II) in 1 and Cu(II) and Pd(II) in 2], four cyanide ligands, one 4aepy ligand and one coordinated ligand (ammine in 1 and aqua in 2) in a distorted tetragonal coordination geometry. The crystal structures of the complexes revealed that three cyanide groups are terminal whereas one different cyanide group behaves as bridging ligand. The most important features of the complexes are the presence of obvious M⋯π [M(II) = Ni(II) or Pd(II … |
| Anahtar Kelimeler |
| 1D complex | 4-(2-Aminoethyl)pyridine complex | Crystal structure | Cyanide complex | M⋯π interaction |
Science Direct
One dimensional coordination polymers with 4 2 aminoethyl pyridine Synthesis crystal structures and spectroscopic properties
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