Zinc(II) and cadmium(II) coordination polymers containing phenylenediacetate and bis(imidazol-1-ylmethyl)benzene linkers: The effect of ligand isomers on the solid state structures
Yazarlar (4)
Güneş Günay Sezer
Bartın Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Andrew D Burrows
University Of Bath, Department Of Chemistry, İngiltere
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Solid State Chemistry (Q2)
Dergi ISSN 0022-4596 Dergi Bilgileri (2017)
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 08-2017
Cilt / Sayı / Sayfa 252 / 1 / 8–21 DOI 10.1016/j.jssc.2017.04.038
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0022459617301573
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
This work presents a systematic investigation of the reactions of o-, m- and p-phenylenediacetic acid with Zn(II)/Cd(II) salts in the presence of different semi-rigid o-, m- and p-bis(imidazol-1-ylmethyl)benzene co-ligands. Fourteen new coordination polymers – {[Zn(μ-opda)(µ-mbix)]·0.5H2O}n (1), {[Zn(μ-mpda)(µ-obix)]·H2O}n (2), {[Zn2(μ-mpda)2(μ-mbix)2]·5H2O}n (3), {[Zn(μ-mpda)(µ-mbix)]·2H2O}n (4), {[Zn(μ-mpda)(µ-pbix)]·0.5H2O}n (5), [Zn(μ-ppda)(μ-obix)]n (6), {[Zn(μ-ppda)(µ-mbix)]·0.5H2O}n (7), {[Zn(μ-ppda)(μ-pbix)]·H2O·DMF}n (8), {[Cd(μ-mpda)(μ-obix)1.5]·H2O}n (9), {[Cd(μ-mpda)(μ-obix)]·H2O}n (10), {[Cd(μ-mpda)(μ-mbix)(H2O)]·H2O}n (11), [Cd(μ3-ppda)(µ-obix)]n (12), [Cd(μ3-ppda)(µ-mbix)]n (13) and [Cd(μ3-ppda)(µ-pbix)]n (14) (o/m/ppda=1,2/1,3-/1,4-phenylenediacetate, o/m/pbix=1,2-/1,3-/1,4-bis(imidazol-1-ylmethyl)benzene) – have been prepared and structurally characterized. Two of the complexes …
Anahtar Kelimeler
Bis(imidazole) derivative | Coordination polymer | Hydrothermal synthesis | Phenylenediacetic acid | Zinc(II) complex Cadmium(II) complex