Chelate ring stacking interactions in the supramolecular assemblies of Zn(ii) and Cd(ii) coordination compounds: a combined experimental and theoretical study
Yazarlar (9)
Farhad Akbari Afkhami
University Of Tabriz
University Of Tabriz
Ali Akbar Khandar
University Of Tabriz
University Of Tabriz
Ghodrat Mahmoudi
University Of Maragheh
University Of Maragheh
Waldemar Maniukiewicz
Lodz University Of Technology, Polonya
Lodz University Of Technology, Polonya
Atash V Gurbanov
Baku State University, Azerbaycan
Baku State University, Azerbaycan
Fedor I Zubkov
Rudn University, Rusya Federasyonu
Rudn University, Rusya Federasyonu
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Antonio Frontera
Universitat De Les Illes Balears, İspanya
Universitat De Les Illes Balears, İspanya
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Crystengcomm (Q1) | ||
| Dergi ISSN | 1466-8033 Dergi Bilgileri (2017) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2017 |
| Cilt / Sayı / Sayfa | 19 / 10 / 1389–1399 | DOI | 10.1039/c6ce02666d |
| Makale Linki | http://xlink.rsc.org/?DOI=C6CE02666D | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The self-assembly of Zn(II) and Cd(II) ions with two isomeric tetradentate ligands, 2-pyridyl-isonicotinoylhydrazone (HL1) and 2-benzoylpyridyl-picolinoylhydrazone (HL2), was studied by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction. The reaction of zinc(II) and cadmium(II) salts with HL1 and HL2 in methanol under solvothermal conditions produced six monomer and one tetranuclear zinc(II) complexes, namely, Zn(HL1)Br2 (1), Zn(HL1)Cl2 (2), [Cd(HL1)2](NO3)2·H2O (3), Cd(HL2)Br2(4), Zn(HL2)Cl2 (5), Zn(HL2)Br2 (6) and [Zn4(L2)4I2][ZnI4]·2H2O (7). The structure of 7 includes a cationic tetranuclear cluster of four zinc ions, four ligands, and two anions, counterbalanced by ZnI42− ions. However, the reaction of zinc(II) and cadmium(II) salts with HL1 under the same conditions produced monomer compounds. Herein, the ligand effects on the complex structures were studied. Hirshfeld … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 38 |
| Scopus | 38 |
| Google Scholar | 40 |