Synthesis, characterization, electrical conductivity and luminescence properties of two copper(II) complexes with tridentate N 2 O chelating ligands containing imine bond
Yazarlar (5)
Öğr. Gör. İlyas Gönül Çukurova Üniversitesi, Türkiye
Burak Ay Çukurova Üniversitesi, Türkiye
Öğr. Gör. Serkan Karaca Çukurova Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Selahattin Serin
Çukurova Üniversitesi, Türkiye
Çukurova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2018) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2018 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-03-2018 |
| Cilt / Sayı / Sayfa | 1156 / 1 / 465–472 | DOI | 10.1016/j.molstruc.2017.12.020 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S002228601731640X | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| In the present study, we describe the synthesis and characterization of two tridentate N2O donor ligands, namely, (E)-2-(((2-(diethylamino)ethyl)imino)methyl)-6-methoxyphenol (HL1) and (E)-2-(((2-(diethylamino)ethyl)imino)methyl)-6-ethoxyphenol (HL2), and their copper(II) complexes, [Cu(L1)(CH3COO)] (1), [Cu(L2)(CH3COO)] (2). They have been synthesized under conventional methods and characterized by elemental analysis, FTIR, 1H and 13C NMR, ICP-OES, TGA and GC/MS analysis. For the morphological analysis field emission scanning electron microscopy (FESEM) was used. The geometry of the copper(II) complexes was determined by single crystal X-ray diffraction analysis. The copper(II) ions are in distorted square-pyramidal coordination environments. Complexes crystallize in monoclinic space group, P21/c. The electrical conductivity and luminescence properties of 1–2 have been investigated. |
| Anahtar Kelimeler |
| Copper (II) complexes | Electrical conductivity | Luminescence | Single crystal X-ray | Soluble Schiff base metal complexes |
Science Direct
Synthesis, characterization, electrical conductivity and luminescence properties of two copper(II) complexes with tridentate N 2 O chelating ligands containing imine bond
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