Synthesis and characterization of new Ag(I) coordination networks based on saccharinate and bis(isopropylimidazole) ligands exhibiting very close C–H⋯Ag interactions
Yazarlar (3)
Prof. Dr. Fatih Semerci Kırklareli Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Hakan Erer Eskişehir Osmangazi Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q2) | ||
| Dergi ISSN | 0277-5387 Dergi Bilgileri (2017) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2017 |
| Cilt / Sayı / Sayfa | 123 / 1 / 316–322 | DOI | 10.1016/j.poly.2016.11.029 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S027753871630612X | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Two Ag(I) coordination networks, formulated as [Ag(sac)(μ-bisopib)]n (1) and [Ag(sac)(μ-pbisopix)]·H2O (2), have been synthesized based on the bis(isopropylimidazole) ligands 1,4-bis(2-isopropyl-1H-imidazol-1-yl)butane (bisopib) and 1,4-bis((2-isopropyl-1H-imidazol-1-yl)methyl)benzene (pbisopix), respectively, along with saccharinate (sac) ligands. All the complexes were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction studies. The X-ray crystallographic studies of 1 and 2 revealed that the Ag(I) ions are μ-bridged by the bis(isopropylimidazole) derivative ligands to generate 1D zig-zag polymer and dinuclear structures, respectively. As far as we know, complex 1 shows the closest C–H⋯Ag interaction distance among similar literature examples. In complex 1 adjacent 1D coordination polymers are further joined by C–H⋯O hydrogen bonds and π⋯π interactions, generating … |
| Anahtar Kelimeler |
| Ag(I) complexes | bis(isopropylimidazole) ligands | Coordination polymers | C–H⋯Ag interaction | Saccharinate complexes |
Science Direct
Synthesis and characterization of new Ag(I) coordination networks based on saccharinate and bis(isopropylimidazole) ligands exhibiting very close C–H⋯Ag interactions
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 5 |
| Scopus | 5 |
| Google Scholar | 6 |