The synthesis of two new Hofmann-type M(3-aminopyridine)2Ni(CN)4 [M = Zn(II) and Cd(II)] complexes and thecharacterization of their crystal structure by various spectroscopicmethods
Yazarlar (3)
Zeki Kartal
Kütahya Dumlupınar Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Abdülkerim Yavuz Dumlupinar Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q3)
Dergi ISSN 0022-2860 Dergi Bilgileri (2018)
Dergi Tarandığı Indeksler SSCI
Makale Dili İngilizce Basım Tarihi 01-2018
Kabul Tarihi Yayınlanma Tarihi 01-11-2018
Cilt / Sayı / Sayfa 1171 / 1 / 578–586 DOI 10.1016/j.molstruc.2018.06.042
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0022286018307439
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
The aim of this work is to obtain new examples of Hofmann-type complexes in single crystal form. Two novel Hofmann-type Zn(3-aminopyridine)2Ni(CN)4 (1) and Cd(3-aminopyridine)2Ni(CN)4 (2) complexes in a single crystal form have been synthesized and characterized by elemental, thermal and vibrational (FT-IR and FT-Raman) analysis. The general information about the structural properties of these Hofmann-type complexes 1 and 2 was acquired from the FT-IR and FT-Raman spectra by considering changes at characteristic peaks of the cyano group and 3-aminopyridine ligand molecule. The thermal behaviors of these Hofmann-type complexes 1 and 2 have also been investigated in the range of (50–600) 0C using the TG and DTG methods. Also, the magnetic susceptibility measurements of these Hofmann-type complexes 1 and 2 were made at the room temperature using the Gouy-balance. The …
Anahtar Kelimeler
3-Aminopyridine | Hofmann-type complexes | Single crystal X-Ray diffraction analysis | Transition metal coordination complexes | Vibrational spectra