Synthesis of phosphine-containing novel Pd(II) and Ni(II) complexes: Electrochemical, photophysical and quantum chemical studies
Yazarlar (5)
Gurbet Yerlikaya
Çukurova Üniversitesi, Türkiye
Çukurova Üniversitesi, Türkiye
Eylül Büşra Tapanyiğit
Çukurova Üniversitesi, Türkiye
Çukurova Üniversitesi, Türkiye
Prof. Dr. Bilgehan Güzel Çukurova Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Gülfeza Kardaş Çukurova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2019) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2019 |
| Cilt / Sayı / Sayfa | 1198 / 1 / 126889–0 | DOI | 10.1016/j.molstruc.2019.126889 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S0022286019309809 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Pd(ll) and Ni(ll) complexes of bis(diphenylphosphinemethyl) aminobutyl, ((Ph2PCH2)2N(CH2)3(CH3)3), were synthesized using Schlenck techniques under nitrogen atmosphere. Synthesized complexes were characterized by using thermal analysis, elemental analyses, 1H NMR, 31P NMR, FT-IR and UV–Vis techniques. Single crystal X-Ray diffraction analysis confirms the structure of the newly synthesized compounds. The electrochemical properties of complexes were studied by using cyclic voltammetry. All complexes exhibited intra-ligand (π→π*) fluorescence in CH2Cl2. Hartree Fock was used to determine the electronic structure and properties of the complexes. Band gaps of the newly synthesized complexes were calculated as 3.19eV and 3.15eV and showed good optical properties. |
| Anahtar Kelimeler |
| Bis(diphenylphosphinomethyl)aminobutyl | Electrochemistry | Hartree Fock | Optical properties | X-ray crystallography |
Science Direct
Synthesis of phosphine-containing novel Pd(II) and Ni(II) complexes: Electrochemical, photophysical and quantum chemical studies
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 7 |
| Scopus | 8 |
| Google Scholar | 10 |