Synthesis, crystal structure and magnetic properties of an octanuclear cerium(III) complex of pyridine-2,6-dicarboxylate
Yazarlar (6)
Shahzad Sharif
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Islam Ullah Khan
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Nadia Jabeen
University Of Engineering And Technology, Lahore, Pakistan
University Of Engineering And Technology, Lahore, Pakistan
Saeed Ahmad
Prince Sattam Bin Abdulaziz University, Suudi Arabistan
Prince Sattam Bin Abdulaziz University, Suudi Arabistan
Bushra Khan
Lahore College For Women University, Pakistan
Lahore College For Women University, Pakistan
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Zeitschrift Fur Naturforschung Section B Journal of Chemical Sciences (Q3) | ||
| Dergi ISSN | 0932-0776 Dergi Bilgileri (2019) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2019 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 31-01-2019 |
| Cilt / Sayı / Sayfa | 74 / 3 / 255–260 | DOI | 10.1515/znb-2018-0178 |
| Makale Linki | http://www.degruyter.com/view/j/znb.2019.74.issue-3/znb-2018-0178/znb-2018-0178.xml | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| An octanuclear compound of cerium(III), [Ce8(Pydc)10(HPydc)4.22H2O].11H2O (1) (Pydc=pyridine-2,6-dicarboxylate anion) was prepared under mild solvothermal conditions and its crystal structure was determined by single-crystal X-ray diffraction. Three kinds of coordination environments are observed, which include: [Ce(Pydc)3], [Ce(Pydc)(H2O)4(O,O)], and [Ce(H2O)7(O,O)]. Each cerium atom in 1 is nine-coordinated but two different geometries are found. The Ce1 and Ce2 atoms exhibit a nearly tricapped trigonal prismatic CeN3O6 geometry, while Ce3 and Ce4 possess CeNO8 and CeO9 coordination polyhedra, which approximate to slightly distorted mono-capped square antiprisms having 12 triangular faces. The Pydc ligands adopt tri-, tetra-, and penta-coordination modes through tridentate chelating and, μ2 and μ3-bridging modes, respectively. The clusters are joined by O–H···O hydrogen bonds to … |
| Anahtar Kelimeler |
| Cerium(III) | Coordinationpolymer | Crystalstruc-ture | Magnetic properties | Pyridine-2,6-dicarboxylate |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 6 |
| Scopus | 4 |
| Google Scholar | 4 |