Iron(III) and Nickel(II) Complexes with S-alkyl (n-C1-6)-thiosemicarbazidato Ligands: Synthesis, Structural Characterization, and Antioxidant Features
Yazarlar (4)
Büşra Kaya Istanbul Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Mustafa Bener İstanbul Üniversitesi-Cerrahpaşa, Türkiye
Bahri Ülküseven
İstanbul Üniversitesi-Cerrahpaşa, Türkiye
İstanbul Üniversitesi-Cerrahpaşa, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2018) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2018 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-09-2018 |
| Cilt / Sayı / Sayfa | 1167 / 1 / 16–22 | DOI | 10.1016/j.molstruc.2018.04.082 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S0022286018305325 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
|
||
| Özet |
| Six of acetylacetone-S-R-thiosemicarbazones (R: methyl, ethyl, propyl, butyl, pentyl or hexyl) were synthesized, and the template reactions resulting in N2O2 type complexes of the thiosemicarbazones with 4-methoxy-salicylaldehyde were carried out in the presence of iron(III) or nickel(II). The thiosemicarbazones and metal complexes were defined by elemental analysis, and infrared, UV–Vis, 1H NMR spectra. Three complexes bearing butyl-pentyl- and hexyl- groups were analyzed by X-Ray diffraction technique. The crystal data demonstrated that the iron complexes are in square pyramidal structure and nickel complexes in square planar structure. To explicate the relationship between the S-alkyl chain length and antioxidant ability, total antioxidant capacity (as TEAC value) and free radical scavenging activity of the compounds have been tested using CUPRAC and DPPH methods, respectively. Furthermore, the … |
| Anahtar Kelimeler |
| Antioxidant capacity | Metal complex | Radical scavenging activity | Structural analysis | Thiosemicarbazone |
Science Direct
Iron(III) and Nickel(II) Complexes with S-alkyl (n-C1-6)-thiosemicarbazidato Ligands: Synthesis, Structural Characterization, and Antioxidant Features
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 22 |
| Scopus | 23 |
| Google Scholar | 25 |