Novel mixed ligand complexes of acesulfame / nicotinamide with some transition metals. Synthesis, crystal structural characterization, and biological properties
Yazarlar (5)
Öğr. Gör. Tuğrul Yıldırım Hitit Üniversitesi, Türkiye
Prof. Dr. Dursun Ali Köse Hitit Üniversitesi, Türkiye
Prof. Dr. Emre Avcı Hitit Üniversitesi, Türkiye
Doç. Dr. Demet Özer Hacettepe Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q3)
Dergi ISSN 0022-2860 Dergi Bilgileri (2019)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 02-2019
Kabul Tarihi Yayınlanma Tarihi 01-01-2019
Cilt / Sayı / Sayfa 1176 / 1 / 576–582 DOI 10.1016/j.molstruc.2018.08.099
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0022286018310482
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
The salt type mixed ligand metal complexes of CoII (I), NiII (II), CuII (III), ZnII (IV) and MnII (V) were synthesized using neutral ligand nicotinamide and anionic ligand acesulfame. The structural characterizations of complexes were performed by using elemental analysis, magnetic susceptibility, solid-state UV–Vis, FTIR spectra, thermoanalytic TG-DTG/DTA, and single crystal X-ray diffraction methods. The complexes of I, III, IV, and V were obtained suitable crystal form for single crystal analysis by SC-XRD diffraction. The complexes of II was believed that the others structures so, the spectroscopic results of all the complexes are suitable for each other. The complexes are salt type compounds, and they have 2 mol nicotinamide ligands as monodentate coordination to metal center by pyridine N atoms and 4 mol aqua ligands in coordination sphere and 2 mol anionic acesulfamate ligands located outside of …
Anahtar Kelimeler
Acesulfame | Biological application | Crystal structure | Mixed ligand complexes | Nicotinamide | Thermal properties