Synthesis and structural analysis of heteronuclear hexacyanochromate(III) complex with tris(2-aminoethyl)amine), [Cd(tren)(Htren)][Cr(CN)6]⋅2H2O
Yazarlar (5)
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Dr. Öğr. Üyesi Elvan Sayın Turkish Standard Institution (Tse), Türkiye
Emir Enönlü
Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q3)
Dergi ISSN 0022-2860 Dergi Bilgileri (2020)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 11-2020
Kabul Tarihi Yayınlanma Tarihi 01-11-2020
Cilt / Sayı / Sayfa 1219 / 1 / 1–7 DOI 10.1016/j.molstruc.2020.128462
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0022286020307870
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
The synthesis and structural investigation of a new heteronuclear hexacyanochromate(III) complex based on amine containing tetradentate ligand tris(2-aminoethyl)amine ligand (tren) are reported. The complex was characterized by spectral (FT-IR and Raman), elemental, thermal analysis (TG, DTG and DTA) as well as single crystal X-ray diffraction (SC-XRD) techniques. From elemental and spectral data, the formulae, [Cd(tren)(Htren)][Cr(CN)6]⋅2H2O (1), for the metal complex has been proposed. Single crystal X-ray diffraction (SC-XRD) measurement showed that the asymmetric unit of 1 consists of one Cd(II) ion, one Cr(III) ion, six cyanide ligands, one tren and one Htren ligands and two crystal water molecules. The structure of 1 presents one of tren ligands was protonated and the coordinated to Cd(II) ion as a monodentate ligand. Other tren ligand was also bonded to Cd(II) ion as a tetradentate ligand to form …
Anahtar Kelimeler
cadmium(II) complex | cyanide complex | heteronuclear complex | Hexacyanochromate(III) complex | tris(2-aminoethyl)amine complex