Iron(III) complex with N2O2-thiosemicarbazidato and azide ligands. Synthesis mechanism, experimental and theoretical studies
Yazarlar (4)
Arş. Gör. Büşra Kaya Istanbul University-Cerrahpasa, Türkiye
Bahri Ülküseven
İstanbul Üniversitesi-Cerrahpaşa, Türkiye
İstanbul Üniversitesi-Cerrahpaşa, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Zarife Sibel ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2019) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2019 |
| Cilt / Sayı / Sayfa | 1191 / 1 / 337–344 | DOI | 10.1016/j.molstruc.2019.04.079 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S002228601930482X | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Reaction of acetylacetone-S-methyl-thiosemicarbazone and 4-methoxy-salicylaldehyde in presence of Fe(ClO4)3 and NaN3 resulted in a mixed ligand complex, [Fe(L)N3], where L is N2O2-chelating thiosemicarbazidato ligand formed by template condensation. The first iron complex of the thiosemicarbazidato structure bearing a nitrogen ligand instead of chlorine in the 5th coordination site of iron(III) was characterized by using elemental analysis and spectroscopic methods. Crystallographic analysis clearly revealed the square pyramidal environment of iron(III) center. To support and compare the experimental data, the molecular geometries, vibrational frequencies, NMR chemical shifts, molecular electrostatic potential surface and HOMO-LUMO energies were performed by using DFT-B3LYP method. Formation of the iron(III) complex was explicated by identification the reaction intermediates using experimental … |
| Anahtar Kelimeler |
| Azide | Iron(III) | Structural analysis | Thiosemicarbazone | XRD DFT |
Science Direct
Iron(III) complex with N2O2-thiosemicarbazidato and azide ligands. Synthesis mechanism, experimental and theoretical studies
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 10 |
| Scopus | 10 |
| Google Scholar | 11 |